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1 свободнорадикальный механизм развития цепи
Polymers: free-radical-chain mechanismУниверсальный русско-английский словарь > свободнорадикальный механизм развития цепи
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2 свободнорадикальный механизм роста цепи
Polymers: free-radical-chain mechanismУниверсальный русско-английский словарь > свободнорадикальный механизм роста цепи
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Free radical halogenation — In organic chemistry, free radical halogenation is a type of halogenation. This chemical reaction is typical of alkanes and alkyl substituted aromatics under application of heat or UV light. The reaction is used for the industrial synthesis of… … Wikipedia
Free radical addition — is an addition reaction in organic chemistry involving free radicals [L.G. Wade s Organic Chemistry 5th Ed. (p 319) Mechanism supplements original.] . The addition may occur between a radical and a non radical, or between two radicals.The basic… … Wikipedia
Living free radical polymerization — is a type of living polymerization where the active polymer chain end is a free radical. Several methods exist. IUPAC recommends[1] to use the term reversible deactivation radical polymerization instead of living free radical polymerization .… … Wikipedia
Radical polymerization — is a type of polymerization in which the reactive center of a polymer chain consists of a radical.The polymerization reaction is initiated by three classes of free radical initiators: * certain compounds that can be broken down in two radicals at … Wikipedia
Radical (chemistry) — Free radical redirects here. For other uses, see Free radical (disambiguation). Moses Gomberg (1866 1947), the founder of radical chemistry Radicals (often referred to as free radicals) are atoms, molecules, or ions with unpaired electrons on an… … Wikipedia
Radical-nucleophilic aromatic substitution — or SRN1 in organic chemistry is a type of substitution reaction in which a certain substituent on an aromatic compound is replaced by a nucleophile through an intermediary free radical species:The substituent X is a halide and nucleophiles can be … Wikipedia
Chain reaction — This article is about chain reactions in chemistry and physics. For other uses, see Chain reaction (disambiguation). A chain reaction is a sequence of reactions where a reactive product or by product causes additional reactions to take place. In… … Wikipedia
Chain growth polymerisation — Chain growth polymerization is a polymerization technique where unsaturated monomer molecules add on to a growing polymer chain one at a time [1]. It can be represented with the chemical equation: where n is the … Wikipedia
Radical clock — In chemistry, a radical clock is a compound that assists in the indirect methodology to determine the kinetics of radical molecule reactions. This involves a unimolecular radical reaction with a known rate constant competing against a bimolecular … Wikipedia
Cobalt mediated radical polymerization — Cobalt based catalysts, when used in radical polymerization, have several main advantages especially in slowing down the reaction rate, allowing for the synthesis of polymers with peculiar properties. As starting the reaction does need a real… … Wikipedia
reaction mechanism — Introduction in chemical reactions (chemical reaction), the detailed processes by which chemical substances are transformed into other substances. The reactions themselves may involve the interactions of atoms (atom), molecules (molecule),… … Universalium